Search results for "Solid solutions"

showing 10 items of 10 documents

Polarization and acoustic properties of barium-modified lead-free potassium–sodium niobate ceramics

2017

The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.

010302 applied physicsFerroelectricsCeramicsMaterials science010308 nuclear & particles physicsGeneral EngineeringAnalytical chemistryElastic propertieschemistry.chemical_elementRelaxorsBarium01 natural scienceschemistryPotassium sodiumDielectric permittivityvisual_artPolarization0103 physical sciencesvisual_art.visual_art_medium:NATURAL SCIENCES:Physics [Research Subject Categories]CeramicPolarization (electrochemistry)Solid solutionsProceedings of the Estonian Academy of Sciences
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Designing Solid Solutions of Enantiomers: Lack of Enantioselectivity of Chiral Naphthalimide Derivatives in the Solid State

2017

The enantiomers of a previously reported naphthalimide derivative are shown in this study to form a solid solution; furthermore, on the basis of the knowledge of solid solution structural aspects other naphthalimide derivatives have been synthesized and shown to lack the enantioselectivity in the solid state. The structural origin of solid solution formation is the same as observed in most of the cases in the literaturequasi-centrosymmetric structures form at nonracemic compositions where the most abundant enantiomer adjusts its conformation to mimic the absent one. Such solid solutions belong to the type showing some enantioselectivity. An extended single crystal X-ray diffraction study o…

ChemistryIntermolecular forceSolid-statechirality02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciences0104 chemical sciencessolid solutionsComputational chemistrycrystal engineerigOrganic chemistryGeneral Materials ScienceDensity functional theoryEnantiomerIsostructural0210 nano-technologyChirality (chemistry)Single crystalSolid solution
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Evidence of nickel ions dimerization in NiWO$_4$ and NiWO$_4$-ZnWO$_4$ solid solutions probed by EXAFS spectroscopy and reverse Monte Carlo simulatio…

2021

G.B. acknowledges the financial support provided by the State Education Development Agency for project No.1.1.1.2/VIAA/3/19/444 (agreement No. 1.1.1.2/16/I/001) realized at the Institute of Solid State Physics, University of Latvia. A.K. and A.K. would like to thank the support of the Latvian Council of Science project No. lzp-2019/1-0071. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.

Condensed Matter - Materials ScienceEXAFSNiWO4solid solutions:NATURAL SCIENCES:Physics [Research Subject Categories]Materials Science (cond-mat.mtrl-sci)FOS: Physical sciencesZnWO4antiferromagnetsreverse Monte Carlo
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Peculiarities of the local structure in new medium- and high-entropy, low-symmetry tungstates

2022

G. Bakradze acknowledges financial support provided by the Latvian Council of Science for project no. 1.1.1.2/VIAA/3/19/444 (agreement no. 1.1.1.2/16/I/001) realized at the Institute of Solid State Physics, University of Latvia. The Institute of Solid State Physics, University of Latvia, as a centre of excellence, has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement no. 739508, project CAMART2.

Condensed Matter - Materials ScienceHigh-entropy oxidesMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciences:NATURAL SCIENCES::Physics [Research Subject Categories]TungstatesGeneral ChemistryCondensed Matter Physics540ddc:540Reverse Monte Carlo methodGeneral Materials ScienceSolid solutionsExtended X-ray absorption fine structure
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Electrocaloric Effect in (1−x)(0.8Na0.5Bi0.5TiO3-0.2BaTiO3)−xCaTiO3 Solid Solutions at High Electric Fields

2022

This research was funded by the Latvian Science Council Fund, grant number lzp-2020/2-0080. The Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme, grant number 739508.

Inorganic ChemistryElectrocaloric effectPhase transitionsMaxwell relationGeneral Chemical Engineering:NATURAL SCIENCES [Research Subject Categories]Dielectric polarizationGeneral Materials ScienceSodium bismuth titanateCondensed Matter Physicssodium bismuth titanate; solid solutions; electrocaloric effect; dielectric polarization; phase transitions; Maxwell relationSolid solutionsCrystals
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Behaviour of thermal expansion of (1-x)Pb(Ni1/3Nb2/3)O3–xPbTiO3 solid solutions

2017

The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.

Materials science010405 organic chemistryferroelectricsGeneral EngineeringThermodynamicsceramics010402 general chemistry01 natural sciencesEstonianrelaxorslanguage.human_languageThermal expansionphase diagram0104 chemical sciencessolid solutionsvisual_art:NATURAL SCIENCES:Physics [Research Subject Categories]visual_art.visual_art_mediumlanguageCeramicthermal expansionPhase diagramSolid solutionProceedings of the Estonian Academy of Sciences
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The influence of Zn$^{2+}$ ions on the local structure and thermochromic properties of Cu$_{1-x}$Zn$_x$MoO$_4$ solid solutions

2021

I. P., A. K. and A. K. would like to thank the support of the Latvian Council of Science project No. lzp-2019/1-0071. I.P. acknowledges the L‘OREAL Baltic “For Women In Science” Program with the support of the Latvian National Commission for UNESCO and the Latvian Academy of Sciences. The experiment at the PETRA III synchrotron was performed within project No. I-20190277 EC. The synchrotron experiments have been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2…

Materials scienceAbsorption spectroscopyMetal ions in aqueous solutionchemistry.chemical_elementFOS: Physical sciences02 engineering and technologyZinc010402 general chemistry01 natural sciences7. Clean energyMaterials Chemistry:NATURAL SCIENCES:Physics [Research Subject Categories]General Materials ScienceCondensed Matter - Materials ScienceThermochromismExtended X-ray absorption fine structureMaterials Science (cond-mat.mtrl-sci)021001 nanoscience & nanotechnologyCopperXANES0104 chemical sciencesCrystallographyEXAFSOctahedronchemistryMechanics of MaterialsMolybdenumCu1-xZnxMoO4ddc:6200210 nano-technologySolid solutionsSolid solution
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Electronic excitations in ZnWO4 and ZnxNi1−x WO4 (x = 0.1 − 0.9) using VUV synchrotron radiation

2011

The photoluminescence spectra and luminescence excitation spectra of pure microcrystalline and nano-sized ZnWO4 as well as the Zn x Ni1−x WO4 solid solutions were studied using vacuum ultraviolet (VUV) synchrotron radiation. The samples were also characterized by x-ray powder diffraction. We found that: (i) the shape of the photoluminescence band at 2.5 eV, being due to radiative electron transitions within the [WO6]6− anions, becomes modulated by the optical absorption of Ni2+ ions in the Zn x Ni1−x WO4 solid solutions; and (ii) no significant change in the excitation spectra of Zn0.9Ni0.1WO4 is observed compared to pure ZnWO4. At the same time, a shift of the excitonic bands to smaller en…

Materials sciencePhotoluminescenceQC1-999General Physics and AstronomySynchrotron radiation02 engineering and technology01 natural sciencesSpectral lineCondensed Matter::Materials Scienceznxni1−x wo4 solid solutions0103 physical sciencesluminescencePhotoluminescence excitationelectronic excitations010302 applied physicsPhysicsznwo4021001 nanoscience & nanotechnologyAtomic electron transitionvuv spectroscopyAtomic physics0210 nano-technologyLuminescenceExcitationPowder diffractiontungstatesOpen Physics
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X-ray absorption and Raman spectroscopy studies of tungstates solid solutions ZncNi1-cWO4 (c=0.0-1.0)

2020

G.B. acknowledges the financial support provided by the State Education Development Agency for project No. 1.1.1.2/VIAA/3/19/444 (agreement No. 1.1.1.2/16/I/001) realized at the Institute of Solid State Physics, University of Latvia. A.K. and A.K. would like to thank the support of the Latvian Council of Science project No. lzp-2019/1-0071. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.

Materials sciencePhysics and Astronomy (miscellaneous)Absorption spectroscopyAnalytical chemistryFOS: Physical sciencesGeneral Physics and AstronomyZnWO47. Clean energy01 natural sciencessymbols.namesakeNiWO40103 physical sciences:NATURAL SCIENCES:Physics [Research Subject Categories]010306 general physicsX-ray ab- sorption spectroscopy010302 applied physicsX-ray absorption spectroscopyCondensed Matter - Materials ScienceX-rayMaterials Science (cond-mat.mtrl-sci)Condensed Matter - Other Condensed MatterMicrocrystallineOctahedronsolid solutionsRaman spectroscopysymbolsAbsorption (chemistry)Raman spectroscopyOther Condensed Matter (cond-mat.other)Solid solutiontungstates
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Revealing the local structure of CuMo1−xWxO4 solid solutions by multi-edge X-ray absorption spectroscopy

2022

I.P. and A.K. would like to thank the support of the Latvian Council of Science project No. lzp-2019/1-0071. I.P. acknowledges the L’OREAL Baltic “For Women In Science Program” with the support of the Latvian National Commission for UNESCO and the Latvian Academy of Sciences. The experiment at the Elettra synchrotron was performed within project No. 20150303. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.

solid solutionsX-ray absorption spectroscopy:NATURAL SCIENCES::Physics [Research Subject Categories]CuMo1−xWxO4reverse Monte Carlo
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